Methyl 2-[(E)-(4-nitrophenyl)hydrazono]-3-oxobutyrate
نویسندگان
چکیده
The mol-ecule of the title compound, C(11)H(11)N(3)O(5), exists as the E isomer as it is stabilized by an intra-molecular hydrogen bond. Except for the methyl H atoms, all atoms lie in special positions on a mirror plane and form a large conjugated system; the methyl H atoms are disordered about the mirror plane. In the crystalline state, bifurcated intra- and inter-molecular N-H⋯O hydrogen bonds and four inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into large perfectly planar sheets. Along the c axis, the N-N bond center approaches the phenyl-ring centroids of its neighbouring mol-ecules above and below to give π-π overlap (at a distance of ca 3.57 Å), thus fusing the mol-ecules into a three-dimensional framework.
منابع مشابه
(E)-Methyl 2-[(4-nitrophenyl)hydrazono]propanoate
The title compound, C(10)H(11)N(3)O(4), is a condensation product of 4-nitro-phenyl-hydrazine and methyl pyruvate. The complete mol-ecule except for the methyl groups can be considered as a conjugated π system. All non-H atoms are approximately coplanar (r.m.s. deviation 0.117 Å). The crystal packing involves an N-H⋯O hydrogen bond and a π-π inter-action between the aromatic rings, with a centr...
متن کاملCrystal structure of ethyl 2-(1H-benzimidazol-2-yl)-2-[2-(4-nitrophenyl)hydrazinylidene]acetate
The title compound, C17H15N5O4, was obtained via the condensation of 3-eth-oxy-2-[2-(4-nitro-phen-yl)hydrazono]-3-oxo-propanoic acid with 1,2-di-amino-benzene. In the mol-ecule, the dihedral angles between the acetate group and the two aromatic subunits (benzimidazole and nitro-phenyl-hydrazone) are 7.35 (9) and 18.23 (9)°, respectively. Intra-molecular N-H⋯O and N-H⋯N contacts occur. In the cr...
متن کامل2-Ethoxy-4-{[(2-nitrophenyl)hydrazono]methyl}phenol
The title compound, C(15)H(15)N(3)O(4), a Schiff base, was obtained from a condensation reaction of 3-eth-oxy-4-hydroxy-benzaldehyde and 2-nitro-phenyl-hydrazine. The mol-ecule is approximately planar, the largest deviation from the mean plane being 0.1449 (16) Å. An intramolecular N-H⋯O inter-action is also present. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules, form...
متن کاملPartial purification and properties of branched-chain 2-oxo acid dehydrogenase of ox liver.
1. A branched-chain 2-oxo acid dehydrogenase was partially purified from ox liver mitochondria. 2. The preparation oxidized 4-methyl-2-oxopentanoate, 3-methyl-2-oxobutyrate and D- and L-3-methyl-2-oxopentanoate. The apparent Km values for the oxo acids and for thiamin pyrophosphate, CoA, NAD+ and Mg2+ were determined. 3. The oxidation of each oxo acid was inhibited by isovaleryl (3-methylbutyry...
متن کامل2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione
In the mol-ecular structure of the title compound, C(21)H(15)N(3)O(4), the inter-planar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenyl-hydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted intra-molecular hydrogen bond (N-H⋯O) and a weak intra-molecular hydrogen bond (C-H⋯N) strongly affe...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008